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Polybasite-M2a2b2c
A structural variant of Polybasite
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Formula:
[Ag6Sb2S7][Ag9CuS4]
Crystal System:
Monoclinic
Unique Identifiers
Mindat ID:
31642
Long-form identifier:
mindat:1:1:31642:0
Chemistry of Polybasite-M2a2b2c
Mindat Formula:
[Ag6Sb2S7][Ag9CuS4]
Element Weights:
Elements listed:
Crystallography of Polybasite-M2a2b2c
Crystal System:
Monoclinic
Class (H-M):
2/m - Prismatic
Space Group:
B2/b
Setting:
C2/c
Cell Parameters:
a = 26.2625(4) Å, b = 15.1623(5) Å, c = 24.1061(6) Å
β = 90.045(5)°
β = 90.045(5)°
Ratio:
a:b:c = 1.732 : 1 : 1.59
Unit Cell V:
9599 Ã
Âģ
Z:
16
Morphology:
Pseudohexagonal tabular, striated crystals.
Comment:
Data for very Ag-rich sample (Bindi & Menchetti, 2009). Evain et al. (2006) give (measured at 100 K) 26.188â
(3), 15.1199â
(18), 23.784â
(3) âŦ, 90° (no s.u. given).
Other Information
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.
Internet Links for Polybasite-M2a2b2c
mindat.org URL:
https://www.mindat.org/min-31642.html
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References for Polybasite-M2a2b2c
Reference List:
Evain, Michel, Bindi, Luca, Menchetti, Silvio (2006) Structural complexity in minerals: twinning, polytypism and disorder in the crystal structure of polybasite, (Ag,Cu)16(Sb,As)2S11. Acta Crystallographica Section B Structural Science, 62 (3) 447-456 doi:10.1107/s010876810600975x
Bindi, Luca, Evain, Michel, Spry, Paul G., Menchetti, Silvio (2007) The pearceite-polybasite group of minerals: Crystal chemistry and new nomenclature rules. American Mineralogist, 92 (5) 918-925 doi:10.2138/am.2007.2440
Bindi, Luca, Keutsch, Frank N., Topa, Dan, Kolitsch, Uwe, Morana, Marta, Tait, Kimberly T. (2023) First occurrence of the M2a2b2c polytype of argentopolybasite, [Ag6Sb2S7][Ag10S4]: Structural adjustments in the Cu-free member of the pearceiteâpolybasite group. Mineralogical Magazine, 87 (4) 561-567 doi:10.1180/mgm.2023.30