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Luinaite-(OH)

A discredited species name
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About Luinaite-(OH)Hide

Formula:
NaFe2+3Al6(Si6O18)(BO3)3(OH)3(OH)
Crystal System:
Monoclinic
Name:
For the type locality, Luina (Heazlewood district, Tasmania, Australia).
Formerly an approved member of the Tourmaline Group, but discredited as a species in 2022.
Results show the occurrence of a triclinic structure for the studied luinaite-(OH) samples, which differs only in terms of a slight structural distortion from typical trigonal tourmaline structure (the topology of the structure is retained).
Triclinic luinaite-(OH) from the type locality (Australia) can be considered as the triclinic dimorph of schorl, as its chemical composition corresponds to schorl, and thus it should be referred as schorl-1A. Similarly, the triclinic sample from the USA can be considered as the triclinic dimorph of oxy-dravite, as its chemical composition corresponds to oxy-dravite, and then is referred to as oxy-dravite-1A.

previous text:
A monoclinic-pseudorhombohedral member of the tourmaline group. The symmetry reduction is caused by cation ordering.
Can be correctly identified only using high-resolution XRD (SXRD) studies. EDS-, EPMA- and standard PXRD-analyses are insufficient for a correct identification of luinaite-(OH).


Unique IdentifiersHide

Mindat ID:
39672
Long-form identifier:
mindat:1:1:39672:7

Similar NamesHide

LenaiteA valid IMA mineral speciesAgFeS2
LeoniteA valid IMA mineral species - grandfatheredK2Mg(SO4)2 · 4H2O
LinnaeiteA valid IMA mineral species - grandfatheredCo2+Co23+S4
Lionite (of Berdell)A synonym of Native Tellurium
Lionite (of Krantz)A synonym of 'Chillagite'
LunnitA synonym of Pseudomalachite

IMA Classification of Luinaite-(OH)Hide

Discredited
IMA Formula:
(Na,◻)(Fe2+,Mg)3Al6(BO3)3Si6O18(OH)4
Approval year:
2009
Approval history:
3.5 IMA 21-L: discreditation of luinaite-(OH), (Na,□)(Fe2+,Mg)3Al6(BO3)3Si6O18(OH)4, a mineral species of the tourmaline supergroup

Proposal 21-L is accepted, and luinaite-(OH) is discredited. This monoclinic tourmaline-type species, with a simplified composition (Na,□)(Fe2+,Mg)3Al6(BO3)3Si6O18(OH)4, was approved with IMA number 2009-046. It is now considered a structurally similar polymorph of schorl, since it only differs in terms of a slight structural distortion from the typical trigonal tourmaline structure.

Classification of Luinaite-(OH)Hide

9.CK.05

9 : SILICATES (Germanates)
C : Cyclosilicates
K : [Si6O18]12- 6-membered single rings, with insular complex anions
61.3.7.

61 : CYCLOSILICATES Six-Membered Rings
3 : Six-Membered Rings with borate groups

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference for Standard
Lui-OHIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Chemistry of Luinaite-(OH)Hide

Mindat Formula:
NaFe2+3Al6(Si6O18)(BO3)3(OH)3(OH)
Element Weights:
Element% weight
O47.085 %
Si15.998 %
Fe15.905 %
Al15.369 %
B3.079 %
Na2.183 %
H0.383 %

Calculated from ideal end-member formula.
O
Si
Fe
Al
B
Na
H

Crystallography of Luinaite-(OH)Hide

Crystal System:
Monoclinic
Class (H-M):
m - Domatic
Space Group:
Bm
Setting:
Cm
Cell Parameters:
a = 10.408(3) Å, b = 15.991(5) Å, c = 7.189(2) Å
β = 117.44(2)°
Ratio:
a:b:c = 0.651 : 1 : 0.45
Unit Cell V:
1,061.88 ų (Calculated from Unit Cell)
Comment:
Strongly pseudorhombohedral.

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
6.47 Å(55)
4.26 Å(52)
4.01 Å(79)
3.51 Å(49)
2.98 Å(48)
2.59 Å(100)
2.06 Å(41)
2.05 Å(44)

Geological EnvironmentHide

Paragenetic Mode(s):
Paragenetic ModeEarliest Age (Ga)
Stage 4b: Highly evolved igneous rocks>3.0
34 : Complex granite pegmatites

First Recorded Occurrence of Luinaite-(OH)Hide

Synonyms of Luinaite-(OH)Hide

Other Language Names for Luinaite-(OH)Hide

Common AssociatesHide

Associations Based on Photo Data:
37 photos of Luinaite-(OH) associated with QuartzSiO2
7 photos of Luinaite-(OH) associated with FluoriteCaF2
4 photos of Luinaite-(OH) associated with FerberiteFeWO4
2 photos of Luinaite-(OH) associated with DolomiteCaMg(CO3)2
2 photos of Luinaite-(OH) associated with TourmalineAD3G6(T6O18)(BO3)3X3Z
1 photo of Luinaite-(OH) associated with MuscoviteKAl2(AlSi3O10)(OH)2
1 photo of Luinaite-(OH) associated with CassiteriteSnO2
1 photo of Luinaite-(OH) associated with SideriteFeCO3
1 photo of Luinaite-(OH) associated with AlbiteNa(AlSi3O8)

Related Minerals - Strunz-mindat GroupingHide

9.CK.AdachiiteCaFe3Al6(Si5AlO18)(BO3)3(OH)3(OH)Trig. 3m : R3m
9.CK.Magnesio-dutrowiteNa(Mg2.5Ti0.5)Al6(Si6O18)(BO3)3(OH)3OTrig. 3m : R3m
9.CK.DarrellhenryiteNa(Al2Li)Al6(Si6O18)(BO3)3(OH)3OTrig. 3m : R3m
9.CK.Fluor-schorlNaFe2+3Al6(Si6O18)(BO3)3(OH)3FTrig. 3m : R3m
9.CK.PrincivalleiteNa(Mn2Al)Al6(Si6O18)(BO3)3(OH)3OTrig. 3m : R3m
9.CK.Alumino-oxy-rossmanite◻Al3Al6(Si5AlO18)(BO3)3(OH)3OTrig. 3m : R3m
9.CK.DutrowiteNa(Fe2+2.5Ti0.5)Al6(Si6O18)(BO3)3(OH)3OTrig. 3m : R3m
9.CK.Ferro-bosiiteNaFe3+3(Al4Fe2+2)(Si6O18)(BO3)3(OH)3OTrig. 3m : R3m
9.CK.BosiiteNaFe3+3(Al4Mg2)(Si6O18)(BO3)3(OH)3OTrig. 3m : R3m
9.CK.Celleriite◻(Mn2+2Al)Al6(Si6O18)(BO3)3(OH)3(OH)Trig. 3m : R3m
9.CK.05FeruviteCaFe2+3(Al5Mg)(Si6O18)(BO3)3(OH)3(OH)Trig. 3m : R3m
9.CK.05Chromium-draviteNaMg3Cr3+6(Si6O18)(BO3)3(OH)3(OH)Trig. 3m : R3m
9.CK.05Fluor-rossmanite◻(Al2Li)Al6(Si6O18)(BO3)3(OH)3FTrig. 3m(32/m) : R3m
9.CK.05Oxy-schorlNa(Fe2+2Al)Al6(Si6O18)(BO3)3(OH)3OTrig. 3m : R3m
9.CK.05Fluor-elbaiteNa(Li1.5Al1.5)Al6(Si6O18)(BO3)3(OH)3FTrig. 3m : R3m
9.CK.05DraviteNaMg3Al6(Si6O18)(BO3)3(OH)3(OH)Trig. 3m : R3m
9.CK.05Fluor-uviteCaMg3(Al5Mg)(Si6O18)(BO3)3(OH)3FTrig. 3m : R3m
9.CK.05Foitite◻(Fe2+2Al)Al6(Si6O18)(BO3)3(OH)3(OH)Trig. 3m : R3m
9.CK.05Vanadio-oxy-draviteNaV3(Al4Mg2)(Si6O18)(BO3)3(OH)3OTrig. 3m : R3m
9.CK.05Fluor-buergeriteNaFe3+3Al6(Si6O18)(BO3)3O3FTrig. 3m : R3m
9.CK.05'Unnamed (F analogue of feruvite)'CaFe2+3(Al5Mg)(Si6O18)(BO3)3(OH)3F
9.CK.05ErtliteNaAl3Al6(Si4B2O18)(BO3)3(OH)3OTrig. 3m : R3m
9.CK.05TsilaisiteNaMn2+3Al6(Si6O18)(BO3)3(OH)3(OH)Trig. 3m : R3m
9.CK.05Fluor-liddicoatiteCa(Li2Al)Al6(Si6O18)(BO3)3(OH)3FTrig. 3m : R3m
9.CK.05UviteCaMg3(Al5Mg)(Si6O18)(BO3)3(OH)3(OH)Trig. 3m : R3m
9.CK.05ElbaiteNa(Li1.5Al1.5)Al6(Si6O18)(BO3)3(OH)3(OH)Trig. 3m : R3m
9.CK.05Fluor-tsilaisiteNaMn2+3Al6(Si6O18)(BO3)3(OH)3FTrig. 3m : R3m
9.CK.05Oxy-foitite◻(Fe2+Al2)Al6(Si6O18)(BO3)3(OH)3OTrig. 3m(32/m) : R3m
9.CK.05LiddicoatiteCa(Li2Al)Al6(Si6O18)(BO3)3(OH)3(OH)Trig. 3m : R3m
9.CK.05Vanadio-oxy-chromium-draviteNaV3(Cr4Mg2)(Si6O18)(BO3)3(OH)3O Trig. 3m : R3m
9.CK.05Rossmanite◻(LiAl2)Al6(Si6O18)(BO3)3(OH)3(OH)Trig. 3m : R3m
9.CK.05Oxy-vanadium-draviteNaV3(V4Mg2)(Si6O18)(BO3)3(OH)3OTrig. 3m : R3m
9.CK.05OleniteNaAl3Al6(Si6O18)(BO3)3O3(OH)Trig. 3m : R3m
9.CK.05'UM2000-64-SiO:BFeHKMg'(K,Na)Fe3+3(Mg2Fe3+4)Si6O18(BO3)3(OH)3O
9.CK.05Magnesio-lucchesiiteCaMg3Al6(Si6O18)(BO3)3(OH)3OTrig. 3m : R3m
9.CK.05PovondraiteNaFe3+3(Mg2Fe3+4)(Si6O18)(BO3)3(OH)3OTrig. 3m : R3m
9.CK.05LucchesiiteCaFe2+3 Al6(Si6O18)(BO3)3(OH)3OTrig. 3m : R3m
9.CK.05Chromo-alumino-povondraiteNaCr3(Al4Mg2)(Si6O18)(BO3)3(OH)3OTrig. 3m : R3m
9.CK.05Fluor-draviteNaMg3Al6(Si6O18)(BO3)3(OH)3FTrig. 3m : R3m
9.CK.05Oxy-draviteNa(Al2Mg)(Al5Mg)(Si6O18)(BO3)3(OH)3OTrig. 3m : R3m
9.CK.05Oxy-chromium-draviteNaCr3(Cr4Mg2)(Si6O18)(BO3)3(OH)3O Trig. 3m : R3m
9.CK.05SchorlNaFe2+3Al6(Si6O18)(BO3)3(OH)3(OH)Trig. 3m : R3m
9.CK.05Magnesio-foitite◻(Mg2Al)Al6(Si6O18)(BO3)3(OH)3(OH)Trig. 3m : R3m
9.CK.05MaruyamaiteK(Al2Mg)(Al5Mg)(Si6O18)(BO3)3(OH)3OTrig. 3m : R3m
9.CK.10Abenakiite-(Ce)Na26Ce6(Si6O18)(PO4)6(CO3)6(SO2)OTrig. 3 : R3
9.CK.15ScawtiteCa7(Si3O9)2CO3 · 2H2OMon. 2/m : B2/m
9.CK.20Thorosteenstrupine(Ca,Th,Mn)3Si4O11F · 6H2O
9.CK.20Steenstrupine-(Ce)Na14Mn2+2Fe3+2Ce6Zr(Si6O18)2(PO4)6(PO3OH)(OH)2 · 2H2OTrig. 3m(32/m) : R3m

Other InformationHide

Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for Luinaite-(OH)Hide

References for Luinaite-(OH)Hide

Localities for Luinaite-(OH)Hide

Showing 13 localities.

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
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Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
Australia (FRL)
 
  • Tasmania
    • Waratah-Wynyard municipality
      • Heazlewood district
        • Luina
IMA Approvals - Sept. 2009. +1 other reference
      • Waratah district
        • Waratah-Mt Bischoff
IMA Approvals - Sept. 2009. +1 other reference
R Bottrill & A Tuma collections
  • Victoria
    • East Gippsland Shire
      • Bendoc
IMA Approvals - Sept. 2009.
Brazil
 
  • Minas Gerais
    • Conselheiro Pena
S. Mills type description in prep
Norway
 
  • Nordland
    • Narvik
Kolitsch et al. (2011) +1 other reference
  • Telemark
    • Porsgrunn
      • Langangen
Kolitsch et al. (2013) +1 other reference
Kolitsch et al. (2013) +1 other reference
  • Vestfold
    • Larvik Commune
      • Malerød
Kolitsch et al. (2013) +1 other reference
      • Tvedalen
        • Tuften
Nordrum (2012) +2 other references
USA
 
  • California
    • San Diego County
      • Pala Mining District
        • Pala
          • Chief Mountain
Mauthner (2024)
Mauthner (2024)
  • Washington
    • King County
      • Snoqualmie Mining District
IMA Approvals - Sept. 2009. +1 other reference
 
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