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Hafnium

72
178.5
Hf
Hafnium

Element Stats

Select a temperature unit to update boiling and melting point values.

Physical

Physical Properties
PropertyValuePropertyValue
Appearancesteel gray
ClassificationTransition MetalsDensity13.281 g/cm³ at STP
Boiling Point4876 KMelting Point2506 K

Atomic

Atomic Properties
PropertyValuePropertyValue
Atomic Number72Atomic Mass178.492
Van Der Waals Radius212Atomic Radius (empirical)159

Electronic & Chemical

Electronic and Chemical Properties
PropertyValuePropertyValue
Electronegativity1.3Electron Affinity17.18 kJ/mol
Electron Configuration1s2 2s2 2p6 3s2 3p6 4s2 3d10 4p6 5s2 4d10 5p6 6s2 4f14 5d2
Oxidation States4, 3, 2, 1, -2
Ionization Energies

Showing all 4 ionization energies.

  1. 658.5 kJ/mol
  2. 1440 kJ/mol
  3. 2250 kJ/mol
  4. 3216 kJ/mol

History

In 1911, French chemist Georges Urbain claimed to have discovered element 72, which he called “celtium.” Although Urbain was right about finding a new element, his descriptions of the element were mostly wrong, so he didn’t truly “discover” the element. In science, it’s important to get the details right!

It wasn’t until 1923 that George Charles de Hevesy and Dirk Coster separated hafnium from zirconium at the University of Copenhagen, officially discovering the element. The two scientists dubbed element 72 “hafnium,” after “Hafnia,” the Latin name for Copenhagen.

Properties

Hafnium is a silvery metal that is ductile, meaning it can be stretched without breaking. It’s also resistant to corrosion and acids. Hafnium and zirconium are a lot alike. However, hafnium is denser and a lot better at absorbing neutrons than zirconium is.

Uses

Because hafnium resists corrosion and is great at absorbing neutrons, it’s often used in nuclear reactors. Hafnium also gets used in gas-filled and incandescent lamps. It’s also useful as a semiconductor, which can be used in computers. When alloyed with other metals, hafnium metals can be made into spacecraft components and other useful objects.

Compounds

Hafnium oxide gets used in semiconductors, which are important in electronics. Hafnium carbide has the highest melting point—more than 3900 °C—among known compounds, but this compound is too expensive to be very useful. At high temperatures, hafnium reacts with carbon, boron, nitrogen, oxygen, silicon, and sulfur.

Forms

More than 40 hafnium isotopes have been observed, but only five of those isotopes (hafnium-176, -177, -178, -179, and -180) are stable (non-radioactive).

Sources

Most hafnium comes from zirconium ores, which are usually about 5% hafnium. Hafnium and zirconium are quite difficult to separate from other elements. Splitting them from each other can be a real headache, too!

Fun Facts

What's my age again?

Hafnium was the key to unlocking the age of the Earth. Researchers used hafnium found in a meteorite to show that Earth’s crust likely formed about 4.5 billion years ago.

It's gettin' hot in here

Tantalum hafnium carbide has the highest melting point of any known compound—over 4200°C! You can't just stick a thermometer in something that hot, so scientists use lasers to melt and measure the temperate of the compound.

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