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Barium oxalate

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Barium oxalate
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.007.471 Edit this at Wikidata
UNII
  • InChI=1S/C2H2O4.Ba/c3-1(4)2(5)6;/h(H,3,4)(H,5,6);/q;+2/p-2 checkY
    Key: GXUARMXARIJAFV-UHFFFAOYSA-L checkY
  • InChI=1/C2H2O4.Ba/c3-1(4)2(5)6;/h(H,3,4)(H,5,6);/q;+2/p-2
    Key: GXUARMXARIJAFV-NUQVWONBAK
  • [Ba+2].[O-]C(=O)C([O-])=O
Properties[1]
BaC2O4
Molar mass 225.345 g·mol−1
Appearance White powder
Odor Odorless
Density 2.658 g/cm3
Melting point 400 °C (752 °F; 673 K) (decomposes)
0.0075 g/100g
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
checkY verify (what is checkYX markN ?)

Barium oxalate is a chemical compound with the chemical formula BaC2O4. It is a barium salt of oxalic acid. It consists of barium cations Ba2+ and oxalate anions C2O2−4. It is a white odorless powder that has rarely been used as a colorant in magnesium-containing pyrotechnic formulas.

Properties

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It is extremely insoluble in water and converts to barium oxide when heated.

Preparation

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The raw materials that are required to prepare barium oxalate are oxalic acid and barium hydroxide (or its octahydrate).

It can be prepared by using an oxalic acid solution and a barium chloride solution, with the reaction as follows:

BaCl2 + H2C2O4 → BaC2O4 + 2 HCl

Safety

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Though largely stable, barium oxalate can be reactive with strong acids. A mild skin irritant, the compound is considered toxic when ingested, causing nausea, vomiting, kidney failure, and injury to the gastrointestinal tract.

References

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  1. Haynes, William M., ed. (2016). CRC Handbook of Chemistry and Physics (97th ed.). Boca Raton, Florida: CRC Press. p. 4–50. ISBN 9781498754293.
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